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Having a well-rounded knowledge of the materials that you are using can be a good in itself -
Insulating materials such as Celotex come with specific detailing instructions when used in the walls of the houses we live in. They are conventionally used in combination with a vapour barrier on the warm side (taping joints achieves the same) and a relatively wide, still air-space on the cold side. So, in order to get maximum benefit, we would put the insulation inside the walls of the hive but separated from the timber by a 50mm gap. Then the whole hive would need to be wrapped with a semi-permeable membrane so that the wood could "breathe".
What a faff all that would be! I think the "compromise" of making cosies out of PIR board or from waterproof, wrapped insulation which isn't rigid, and fixing that up, close to the hive body, is a good use of materials and we now have plenty of user-evidence that it reliably achieves the main objective.....if that objective is the successful wintering of bees.