Where water is stored, prior to heating, is a potential for bacteria and contaminants. A quick look in some of the cold water tanks in attics might horrifying you. I myself have been making progressive changes to a 30 year old system. New boilers, addition of some wet underfloor, unvented on the heating side. The next stage will be a decent amount of work and that is an anvented water storage cylinder, this will provide mains pressure and none of the water will ever be exposed to air prior to heating, much like a combie system. That should be a big plus both for health and a decent shower pressure.