It might well work OK but can be a disaster, especially for a beginner.
For a start you need lots of bees. Second, the emergency queen cells produced may not result in a good queen. Thirdly the frame must have eggs and /or young brood present.
A much better way is to build up your colony and either use queen cells when they are about to swarm, or better still, to induce the bees to draw cells which will be far better than emergency cells (oops, no queen - we're dead if we don't do something fast, scenario) by separating the brood from the queen but leaving contact within the hive.
The usual way is to have a second brood box and place a super, with frames, in beteen the two. Restrict the queen to the bottom brood box and the bees in the upper box (with brood and eggs) will draw supercedure cells which can then be split off with lots of house bees and allowed to continue creating a new colony. Simple really.
A few details like feeding, bees going back to the original site, preventing robbing, wasp attack (later in the season) etc., but basically a simple procedure.
Queen rearing in any other form with only the one hive is just a little too ambitious. Start simply and progress to queen rearing when you have more colonies.
Regardes, RAB